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  6. 1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

Catalog Number aab2116603
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Quantity:
1 g
5 g
25 g
12150-46-8
C34H28FeP2
554.39
MFCD00001422
KZPYGQFFRCFCPP-UHFFFAOYSA-N
λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
[Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
12150-46-8
C34H28FeP2
554.39
MFCD00001422
KZPYGQFFRCFCPP-UHFFFAOYSA-N
λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
[Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1

Description

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY
Melting Point ∽182°C (decomposition)
Assay Percent Range 0.97
Quantity 1 g
Sensitivity Air sensitive
Solubility Information Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water.
Formula Weight 554.4
Percent Purity 97%
Chemical Name or Material 1, 1'-Bis(diphenylphosphino)ferrocene

Safety and Handling

Hazard Category H301-H312-H332
Hazard Statement GHS H Statement
H315-H319-H335
Precautionary Statement P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P312-P330-P363-P501c
DOTInformation Hazard Class: 6.1; Packaging Group: III
TSCA No
storageNote1 Air Sensitive
Recommended Storage Keep cold; Store under Argon
SDS

RUO – Research Use Only

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