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Alfa Aesar™ (1S,2R)-(-)-10,2-Camphorsultam, 99%

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Quantity:
1g
5g
25g
94594-90-8
C10H17NO2S
215.311
MFCD00066271
DPJYJNYYDJOJNO-SZBHIRRCSA-N
5r,7r-10,10-dimethyl-3??-thia-4-azatricyclo 5.2.1.0 1 ,? decane-3,3-dione,--10,2-camphorsultam;--exo-10,2-bornanesultam; 3as-3a,a,6,a,7a,a-hexahydro-8,8-dimethyl-3h-3a,6-methano-2,1-benzisothiazole-2,2-dioxide; 1s,5r-10,10-dimethyl-3-thia-4-azatricyclo 5.2.1.01,5 decane 3,3-dioxide
54579826
CC1(C2CCC13CS(=O)(=O)NC3C2)C
94594-90-8
C10H17NO2S
215.311
MFCD00066271
DPJYJNYYDJOJNO-SZBHIRRCSA-N
5r,7r-10,10-dimethyl-3??-thia-4-azatricyclo 5.2.1.0 1 ,? decane-3,3-dione,--10,2-camphorsultam;--exo-10,2-bornanesultam; 3as-3a,a,6,a,7a,a-hexahydro-8,8-dimethyl-3h-3a,6-methano-2,1-benzisothiazole-2,2-dioxide; 1s,5r-10,10-dimethyl-3-thia-4-azatricyclo 5.2.1.01,5 decane 3,3-dioxide
54579826
CC1(C2CCC13CS(=O)(=O)NC3C2)C
Applications
(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents.
Optical Rotation −33° (c=1 in Ethanol)
Quantity 5g
Melting Point 181°C to 186°C
Beilstein 83811
Solubility Information Slightly soluble in water.
Formula Weight 215.32
Percent Purity 99%
Chemical Name or Material (1S,2R)-(-)-10,2-Camphorsultam

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

TSCA : No

Recommended Storage : Ambient temperatures