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Alfa Aesar™ 3-Bromopropionyl chloride, tech. 90%

Manufacturer:  Alfa Aesar™ A1084622

Quantity 100g

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Catalog No. AAA1084622

This item has been discontinued by the manufacturer and is no longer available. Please call customer service for assistance: 1-800-766-7000.


Specifications

Description

Applications
3-Bromopropionyl chloride acts as an acrylate synthon by reaction with 2-oxazolidinone, followed by base-promoted elimination to form a Diels-Alder dienophile. Brominated poly (ethylene glycol) methacrylate (v-PEG-Br) which was synthesized by the reaction of poly (ethyleneglycol) methacrylate, v-PEG-OH with Mn = 526 Dalton and 3-bromopropionyl chloride. Used in the reduction of organic compounds by mixed hydrides. Used as reagent in Chroman and tetrahydroquinoline ureas as potent TRPV1 antagonists. Reaction of veratrole with 3- bromopropionyl chloride led to the formation of 15 in 82% yield, which on treatment with the Tebbe reagent13 led to the formation of styryl bromide 16 in 93% yield. Used in the preparation of ome new mono- and di-nitrogen-containing monobenzo-crowns. 3-Bromopropionyl chloride was used in the preparation of 1-chloro-4-bromo-2-butanone.

Solubility
Reacts with water.

Notes
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.
Description & Specifications

Chemical Identifiers

15486-96-1
171.43
UN3265
3-Bromopropionyl chloride
C3H4BrClO
MFCD00000746
605453
Technical Grade

Specifications

15486-96-1
171.43
UN3265
54° to 56°C (14mmHg)
79°C (174°F)
90%
C3H4BrClO
MFCD00000746
605453
100g
3-Bromopropionyl chloride
Technical Grade

Safety and Handling

SDS & Safety Documents

GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.

GHS P Statement
P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

TSCA : TSCA

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