Alfa Aesar™ 3-Bromopropionyl chloride, tech. 90%

Manufacturer: Alfa Aesar™ A1084614

Quantity 25g

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Catalog No. AAA1084614

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This item has been discontinued by the manufacturer and is no longer available. Please call customer service for assistance: 1-800-766-7000. 


    Chemical Identifiers

    CAS 15486-96-1
    Molecular Formula C3H4BrClO
    Formula Weight 171.43g/mol
    MDL Number MFCD00000746
    UN Number UN3265
    Beilstein 605453
    Chemical Name or Material 3-Bromopropionyl chloride
    Grade Technical Grade

    Specifications

    Boiling Point 54° to 56°C (14mmHg)
    Quantity 25g
    Flash Point 79°C (174°F)
    CAS 15486-96-1
    Molecular Formula C3H4BrClO
    Formula Weight 171.43g/mol
    MDL Number MFCD00000746
    UN Number UN3265
    Beilstein 605453
    Health Hazard 1 Danger
    Health Hazard 2 GHS H Statement
    H314-H318-H227
    Causes severe skin burns and eye damage.
    Causes serious eye damage.
    Combustible liquid.
    Health Hazard 3 GHS P Statement
    P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a
    Keep away from heat/sparks/open flames/hot surfaces.
    - No smoking.
    Do not breathe dust/fume/gas/mist/vapors/spray.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
    Continue rinsing.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.
    DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
    TSCA TSCA
    Chemical Name or Material 3-Bromopropionyl chloride
    Assay 90%
    Grade Technical Grade

    Description

    Applications
    3-Bromopropionyl chloride acts as an acrylate synthon by reaction with 2-oxazolidinone, followed by base-promoted elimination to form a Diels-Alder dienophile. Brominated poly (ethylene glycol) methacrylate (v-PEG-Br) which was synthesized by the reaction of poly (ethyleneglycol) methacrylate, v-PEG-OH with Mn = 526 Dalton and 3-bromopropionyl chloride. Used in the reduction of organic compounds by mixed hydrides. Used as reagent in Chroman and tetrahydroquinoline ureas as potent TRPV1 antagonists. Reaction of veratrole with 3- bromopropionyl chloride led to the formation of 15 in 82% yield, which on treatment with the Tebbe reagent13 led to the formation of styryl bromide 16 in 93% yield. Used in the preparation of ome new mono- and di-nitrogen-containing monobenzo-crowns. 3-Bromopropionyl chloride was used in the preparation of 1-chloro-4-bromo-2-butanone.

    Solubility
    Reacts with water.

    Notes
    Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.

    GHS H Statement
    H314-H318-H227
    Causes severe skin burns and eye damage.
    Causes serious eye damage.
    Combustible liquid.

    GHS P Statement
    P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a
    Keep away from heat/sparks/open flames/hot surfaces.
    - No smoking.
    Do not breathe dust/fume/gas/mist/vapors/spray.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
    Continue rinsing.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.

    Danger

    SDS & Safety Documents

  • Description & Specifications
  • Safety and Handling

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