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Alfa Aesar™ 9-BBN monomer, 97%, 0.5M in THF

Manufacturer:  Alfa Aesar™ H52287AE

Quantity 100mL

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Catalog No. AAH52287AE


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Specifications

Description

Applications
9-BBN monomer acts as a selective hydroboration reagent in synthetic organic chemistry. It is employed in Suzuki reactions as well as in the preparation of terminal alcohols by the region selective addition of alkenes followed by oxidative cleavage using hydrogen peroxide. It is also used in copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides. It acts as a protecting group for alkenes. Further, it is used as a reactant for Hetero-Diels-Alder reaction for the synthesis of spirocyclic alkaloids. In addition to this, it is used in intramolecular insertion of alkenes into palladium-nitrogen bonds.

Solubility
Miscible with ether, hexane, benzene, toluene, carbon tetrachloride, chloroform, dimethylsulfide and dichloromethane. Slightly miscible with cyclohexane, dimethoxyethane, diglyme and dioxane.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents, acids and alcohols.
Description & Specifications

Chemical Identifiers

280-64-8
122.02
UN3399
9-Borabicyclo[3.3.1]nonane monomer
C8H15B
MFCD00074742
605509
9-BBN monomer

Specifications

280-64-8
122.02
UN3399
9-Borabicyclo[3.3.1]nonane monomer
100mL
Ether-like
97%
C8H15B
MFCD00074742
605509
0.5M in THF
−19°C (−2°F)
9-BBN monomer

Safety and Handling

SDS & Safety Documents

GHS H Statement
H225-H261-H351-H319-H335
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Suspected of causing cancer.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

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