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  6. Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Catalog Number p-7048276
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Quantity:
0.25 g
1 g
12012-95-2
C6H10Cl2Pd2
365.89
MFCD00044874
PENAXHPKEVTBLF-UHFFFAOYSA-L
allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
61538
chloropalladium(1+);prop-1-ene
Cl[Pd].Cl[Pd].c:c:c.c:c:c
12012-95-2
C6H10Cl2Pd2
365.89
MFCD00044874
PENAXHPKEVTBLF-UHFFFAOYSA-L
allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
61538
chloropalladium(1+);prop-1-ene
Cl[Pd].Cl[Pd].c:c:c.c:c:c

Description

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY
Melting Point 120°C (decomposition)
Color Yellow
Quantity 0.25 g
Beilstein 4124623
Sensitivity Air and moisture sensitive
Solubility Information Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water.
Formula Weight 365.85
Concentration or Composition (by Analyte or Components) Pd 56.0% min.
Physical Form Powder
Chemical Name or Material Allylpalladium(II) chloride dimer

Safety and Handling

Hazard Category H315-H319
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362
EINECSNumber 234-579-8
RTECSNumber RT3510000
TSCA No
storageNote1 2°C to 8°C
Recommended Storage Keep cold; Store under Nitrogen
SDS

RUO – Research Use Only

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