Alfa Aesar™ Benzyl 2,2,2-trichloroacetimidate, 98%

Manufacturer: Alfa Aesar™ A1238714

Quantity 25g

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Catalog No. AAA1238714

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    Chemical Identifiers

    CAS 81927-55-1
    Molecular Formula C9H8Cl3NO
    Formula Weight 252.53g/mol
    MDL Number MFCD00000805
    Beilstein 2525375
    Synonym 2,2,2-Trichloroacetimidic acid benzyl ester
    Chemical Name or Material Benzyl 2,2,2-trichloroacetimidate

    Specifications

    Boiling Point 110° to 114°C (0.5mmHg)
    Quantity 25g
    Flash Point >110°C (230°F)
    CAS 81927-55-1
    Molecular Formula C9H8Cl3NO
    Formula Weight 252.53g/mol
    MDL Number MFCD00000805
    Beilstein 2525375
    Synonym 2,2,2-Trichloroacetimidic acid benzyl ester
    Health Hazard 1 Warning
    Health Hazard 2 GHS H Statement
    H315-H319-H335
    Causes skin irritation.
    Causes serious eye irritation.
    May cause respiratory irritation.
    Health Hazard 3 GHS P Statement
    P261-P280-P305+P351+P338-P304+P340-P405-P501a
    Avoid breathing dust/fume/gas/mist/vapors/spray.
    Wear protective gloves/protective clothing/eye protection/face protection.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
    Continue rinsing.
    IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.
    Recommended Storage 2°C to 8°C
    Chemical Name or Material Benzyl 2,2,2-trichloroacetimidate
    Assay 98%

    Description

    Applications
    Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.

    Solubility
    Miscible with cyclohexane/dichloromethane.

    Notes
    Moisture and light sensitive. Incompatible with strong oxidizing agents and strong acids.

    GHS H Statement
    H315-H319-H335
    Causes skin irritation.
    Causes serious eye irritation.
    May cause respiratory irritation.

    2°C to 8°C

    GHS P Statement
    P261-P280-P305+P351+P338-P304+P340-P405-P501a
    Avoid breathing dust/fume/gas/mist/vapors/spray.
    Wear protective gloves/protective clothing/eye protection/face protection.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
    Continue rinsing.
    IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.

    Warning

    SDS & Safety Documents

  • Description & Specifications
  • Safety and Handling

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