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  6. Bis(1,5-cyclooctadiene)nickel(0), Thermo Scientific Chemicals

Bis(1,5-cyclooctadiene)nickel(0), Thermo Scientific Chemicals

Catalog Number AA3923404
Click to view available options
Quantity:
2 g
10 g
1295-35-8
C16H24Ni
275.06
MFCD00058902
JRTIUDXYIUKIIE-KZUMESAESA-N
bis 1,5-cyclooctadiene nickel 0, bis 1,5-cyclooctadiene nickel, ni cod 2, ccris 5973, bis cyclooctadiene nickel 0, nickel, bis 1,5-cyclooctadiene, bis cyclooctadiene nickel, 1z,5z-cycloocta-1,5-diene; nickel, nickel biscod, pubchem16018
6433264
[Ni].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1
1295-35-8
C16H24Ni
275.06
MFCD00058902
JRTIUDXYIUKIIE-KZUMESAESA-N
bis 1,5-cyclooctadiene nickel 0, bis 1,5-cyclooctadiene nickel, ni cod 2, ccris 5973, bis cyclooctadiene nickel 0, nickel, bis 1,5-cyclooctadiene, bis cyclooctadiene nickel, 1z,5z-cycloocta-1,5-diene; nickel, nickel biscod, pubchem16018
6433264
[Ni].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

Description

Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and is used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. Also, it is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY
Melting Point 60°C (decomposition)
Color Yellow
Odor Odorless
Quantity 2 g
UN Number UN1325
Sensitivity Air and light sensitive
Solubility Information Soluble in benzene,toluene,terahydrofuran,ether,dimethyl formamide,hexamethylphosphoramide,N-methylpyrrolidinone. Insoluble in water.
IUPAC Name bis((1Z,5Z)-cycloocta-1,5-diene) nickel
Formula Weight 275.06
Physical Form Crystalline
Chemical Name or Material Bis(1,5-cyclooctadiene)nickel(0)
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Safety and Handling

Hazard Category H228-H317-H350
Hazard Statement GHS H Statement
H228-H350-H317
Flammable solid.
May cause cancer.
May cause an allergic skin reaction.
Precautionary Statement P201-P202-P210-P240-P241-P261-P270-P272-P280-P302+P352-P308+P313-P333+P313-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 4.1; Packing Group: II; Proper Shipping Name: FLAMMABLE SOLIDS, ORGANIC, N.O.S.
EINECSNumber 215-072-0
RTECSNumber QR6135000
TSCA No
Recommended Storage Ambient temperatures; Store under Nitrogen
SDS

RUO – Research Use Only

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