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Borane-dimethyl sulfide complex, 2M in toluene, packaged under Argon in resealable ChemSeal™ bottles, Thermo Scientific Chemicals
Description
Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
- Packaged under Argon
Specifications
| Color | Colorless |
| Density | 0.856 g/mL |
| Flash Point | 7°C (45°F) |
| Packaging | ChemSeal™ bottles |
| Linear Formula | (CH3)2S·BH3 |
| Quantity | 100 mL |
| UN Number | UN3399 |
| Beilstein | 3663489 |
| Sensitivity | Air and moisture sensitive |
| Solubility Information | It reacts with water. Miscible with diethyl ether,methylene chloride,hexane,heptane,petroleum ether,tetrahydrofuran,diglyme,benzene,toluene and xylene. |
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Safety and Handling
| Hazard Category | H225-H260-H302-H304-H315-H318-H335-H336-H361d-H373 |
| Hazard Statement | GHS H Statement H225-H260-H300-H304-H361-H373-H314-H336 Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. Fatal if swallowed. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. |
| Precautionary Statement | P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P331-P332+P313-P335 |
| DOTInformation | Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE |
| TSCA | Yes |
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| Recommended Storage | Ambient temperatures; Store under Argon |
RUO – Research Use Only
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