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Alfa Aesar™ Catecholborane, 50% w/w in toluene (98% dry wt.)

Manufacturer:  Alfa Aesar™ H3023414

Quantity 25g

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Catalog No. AAH3023414


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Specifications

Description

Applications
Employed in organic synthesis. Addition of catecholborane to vinylarenes in the presence of Wilkinson ft.s catalyst, gives Markovnikov hydroboration products exclusively, whereas the corresponding reaction with a-substituted vinylarenesgivesgood yields of vinylboronate. Hydroboration with catecholborane, followed by treatment with easily available reagents such as alkenyl sulfones or alkynyl phenyl sulfones in the presence of a radical initiator, represents an effective and simple one-pot procedure for direct vinylation, formylation, and cyanation. Catecholborane may be used as a stereoselective reducing agent when converting β-hydroxy ketones to syn 1,3-diols.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from water, moisture.
Description & Specifications

Chemical Identifiers

274-07-7
119.92
UN2924
Catecholborane
C6H5BO2
MFCD00005846
1,3,2-Benzodioxaborole

Specifications

50% w/w in toluene
274-07-7
119.92
UN2924
Catecholborane
25g
C6H5BO2
MFCD00005846
1,3,2-Benzodioxaborole
98%, (dry wt.)

Safety and Handling

SDS & Safety Documents

GHS H Statement
H225-H304-H361-H373-H314-H336
Highly flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.

GHS P Statement
P210-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

TSCA : TSCA

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