Alfa Aesar™ Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals

Manufacturer: Alfa Aesar™ H2588303

Quantity 1g

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Catalog No. AAH2588303

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    Chemical Identifiers

    CAS 142421-57-6
    Molecular Formula C16H6ClF12P
    Formula Weight 492.63g/mol
    MDL Number MFCD01630852
    UN Number UN3265
    Synonym Bis[3,5-bis(trifluoromethyl)phenyl]chlorophosphine
    Chemical Name or Material Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine

    Specifications

    Quantity 1g
    CAS 142421-57-6
    Molecular Formula C16H6ClF12P
    Formula Weight 492.63g/mol
    MDL Number MFCD01630852
    UN Number UN3265
    Synonym Bis[3,5-bis(trifluoromethyl)phenyl]chlorophosphine
    Health Hazard 1 Danger
    Health Hazard 2 GHS H Statement
    H314-H318
    Causes severe skin burns and eye damage.
    Causes serious eye damage.
    Health Hazard 3 GHS P Statement
    P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
    Do not breathe dust/fume/gas/mist/vapors/spray.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.
    DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
    Chemical Name or Material Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine
    Assay ≥98%, may contain suspended dimethylamine hydrochloride crystals

    Description

    Applications
    Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

    Solubility
    Reacts with water.

    Notes
    Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.

    GHS H Statement
    H314-H318
    Causes severe skin burns and eye damage.
    Causes serious eye damage.

    GHS P Statement
    P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
    Do not breathe dust/fume/gas/mist/vapors/spray.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.

    Danger

    SDS & Safety Documents

  • Description & Specifications
  • Safety and Handling

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