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  7. Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%, Thermo Scientific Chemicals

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%, Thermo Scientific Chemicals

Catalog Number AA33657MD
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Quantity:
250 mg
12354-85-7
C20H30Cl4Rh2
618.07
MFCD00061552
QNIVKTTWBMFSBR-UHFFFAOYSA-J
Pentamethylcyclopentadienylrhodium(III) chloride dimer
74222901
1,2,3,4,5-pentamethylcyclopenta-1,3-diene;rhodium(2+);tetrachloride
[Cl-].[Cl-].[Cl-].[Cl-].[Rh++].[Rh++].C[C]1C(C)=C(C)C(C)=C1C.C[C]1C(C)=C(C)C(C)=C1C
12354-85-7
C20H30Cl4Rh2
618.07
MFCD00061552
QNIVKTTWBMFSBR-UHFFFAOYSA-J
Pentamethylcyclopentadienylrhodium(III) chloride dimer
74222901
1,2,3,4,5-pentamethylcyclopenta-1,3-diene;rhodium(2+);tetrachloride
[Cl-].[Cl-].[Cl-].[Cl-].[Rh++].[Rh++].C[C]1C(C)=C(C)C(C)=C1C.C[C]1C(C)=C(C)C(C)=C1C

Description

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY
Melting Point >300°C
Color Red
Odor Odorless
Quantity 250 mg
Solubility Information Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Formula Weight 618.08
Percent Purity 99%
Physical Form Powder
Chemical Name or Material Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H301-H315-H319-H335
Toxic if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
EINECSNumber 625-704-0
TSCA No
Recommended Storage Ambient temperatures
SDS

RUO – Research Use Only

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