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Alfa Aesar™ Diethyl acetone-1,3-dicarboxylate, 96%

Manufacturer:  Alfa Aesar™ A1093318

Quantity 50g

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Catalog No. AAA1093318


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Specifications

Description

Applications
Synthesis of 1-substituted 4-ethoxycarbonyl-5- (ethoxycarbonylmethyl) pyrazoles Diethyl acetone-1, 3-dicarboxylate reacts with N, N-dimethylforma- mide dimethyl acetal (DMFDMA) in ethanol at room temperature. Unexpected product dichotomy is produced in the Biginelli-like condensation of 2-hydroxybenzaldehyde with urea or thiourea and dimethyl or diethyl acetone-1,3-dicarboxylate, respectively, as active methylene components. Ethyl 2-amino-4-(2-ethoxy-2-oxoethyl)thiazole-5-carboxylate (2a), prepared from diethylacetone-1,3-dicarboxylate, sulfuryl chloride and thiourea. Synthesis of diethyl 2,2-diethyl-3,5-dioxopimelate by the reaction of ethyl 3-chloro-3-oxo-2,2-dimethylpropionate with diethyl acetone-1,3-dicarboxylate.

Solubility
Insoluble in water and soluble in alcohol, ester, benzene.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Description & Specifications

Chemical Identifiers

105-50-0
202.21
640146
Diethyl acetone-1,3-dicarboxylate
C9H14O5
MFCD00009200
Acetone-1,3-dicarboxylic acid diethyl ester; Diethyl 3-oxoglutarate

Specifications

50g
C9H14O5
MFCD00009200
640146
Acetone-1,3-dicarboxylic acid diethyl ester; Diethyl 3-oxoglutarate
96%
105-50-0
202.21
134° to 135°C (10mmHg)
86°C (186°F)
Diethyl acetone-1,3-dicarboxylate

Safety and Handling

SDS & Safety Documents

GHS H Statement
H227
Combustible liquid.

GHS P Statement
P210-P280-P370+P378a-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Wear protective gloves/protective clothing/eye protection/face protection.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place.
Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Warning

TSCA : TSCA

Recommended Storage : 2°C to 8°C

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