Alfa Aesar™ Diethyl acetone-1,3-dicarboxylate, 96%

Manufacturer: Alfa Aesar™ A10933-18

Quantity 50g

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Catalog No. AAA1093318

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    Chemical Identifiers

    CAS 105-50-0
    Molecular Formula C9H14O5
    Formula Weight 202.21g/mol
    MDL Number MFCD00009200
    Beilstein 640146
    Synonym Acetone-1,3-dicarboxylic acid diethyl ester; Diethyl 3-oxoglutarate
    Chemical Name or Material Diethyl acetone-1,3-dicarboxylate

    Specifications

    Boiling Point 134° to 135°C (10mmHg)
    Flash Point 86°C (186°F)
    Quantity 50g
    CAS 105-50-0
    Molecular Formula C9H14O5
    Formula Weight 202.21g/mol
    MDL Number MFCD00009200
    Beilstein 640146
    Synonym Acetone-1,3-dicarboxylic acid diethyl ester; Diethyl 3-oxoglutarate
    Health Hazard 1 Warning
    Health Hazard 2 GHS H Statement
    H227
    Combustible liquid.
    Health Hazard 3 GHS P Statement
    P210-P280-P370+P378a-P403+P235-P501a
    Keep away from heat/sparks/open flames/hot surfaces.
    - No smoking.
    Wear protective gloves/protective clothing/eye protection/face protection.
    In case of fire: Use for extinction: CO2, powder or water spray.
    Store in a well-ventilated place.
    Keep cool.
    Dispose of contents/container in accordance with local/regional/national/international regulations.
    Recommended Storage 2°C to 8°C
    TSCA TSCA
    Chemical Name or Material Diethyl acetone-1,3-dicarboxylate
    Assay 96%

    Description

    Applications
    Synthesis of 1-substituted 4-ethoxycarbonyl-5- (ethoxycarbonylmethyl) pyrazoles Diethyl acetone-1, 3-dicarboxylate reacts with N, N-dimethylforma- mide dimethyl acetal (DMFDMA) in ethanol at room temperature. Unexpected product dichotomy is produced in the Biginelli-like condensation of 2-hydroxybenzaldehyde with urea or thiourea and dimethyl or diethyl acetone-1,3-dicarboxylate, respectively, as active methylene components. Ethyl 2-amino-4-(2-ethoxy-2-oxoethyl)thiazole-5-carboxylate (2a), prepared from diethylacetone-1,3-dicarboxylate, sulfuryl chloride and thiourea. Synthesis of diethyl 2,2-diethyl-3,5-dioxopimelate by the reaction of ethyl 3-chloro-3-oxo-2,2-dimethylpropionate with diethyl acetone-1,3-dicarboxylate.

    Solubility
    Insoluble in water and soluble in alcohol, ester, benzene.

    Notes
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

    GHS H Statement
    H227
    Combustible liquid.

    2°C to 8°C

    GHS P Statement
    P210-P280-P370+P378a-P403+P235-P501a
    Keep away from heat/sparks/open flames/hot surfaces.
    - No smoking.
    Wear protective gloves/protective clothing/eye protection/face protection.
    In case of fire: Use for extinction: CO2, powder or water spray.
    Store in a well-ventilated place.
    Keep cool.
    Dispose of contents/container in accordance with local/regional/national/international regulations.

    Warning

    SDS & Safety Documents

  • Description & Specifications
  • Safety and Handling

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