Alfa Aesar™ (+)-Diethyl L-tartrate, 98%

Manufacturer: Alfa Aesar™ A1064136

Quantity 500g

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Catalog No. AAA1064136

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    Chemical Identifiers

    CAS 87-91-2
    Molecular Formula C8H14O6
    Formula Weight 206.19g/mol
    MDL Number MFCD00009143
    Beilstein 1727145
    Merck Index 14,3855
    Synonym L-Tartaric acid diethyl ester
    Chemical Name or Material (+)-Diethyl L-tartrate

    Specifications

    Quantity 500g,500g
    Boiling Point 280°C
    Melting Point 17°C
    Flash Point 93°C (199°F)
    Optical Rotation +27° (c=1 in water)
    CAS 87-91-2
    Molecular Formula C8H14O6
    Formula Weight 206.19g/mol
    MDL Number MFCD00009143
    Beilstein 1727145
    Merck Index 14,3855
    Synonym L-Tartaric acid diethyl ester
    Health Hazard 1 Warning
    Health Hazard 2 GHS H Statement
    H227
    Combustible liquid.
    Health Hazard 3 GHS P Statement
    P210-P280-P370+P378a-P403+P235-P501a
    Keep away from heat/sparks/open flames/hot surfaces.
    - No smoking.
    Wear protective gloves/protective clothing/eye protection/face protection.
    In case of fire: Use for extinction: CO2, powder or water spray.
    Store in a well-ventilated place.
    Keep cool.
    Dispose of contents/container in accordance with local/regional/national/international regulations.
    TSCA TSCA
    Chemical Name or Material (+)-Diethyl L-tartrate
    Assay 98%

    Description

    Applications
    (+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

    Solubility
    Fully miscible in water.

    Notes
    Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

    GHS H Statement
    H227
    Combustible liquid.

    GHS P Statement
    P210-P280-P370+P378a-P403+P235-P501a
    Keep away from heat/sparks/open flames/hot surfaces.
    - No smoking.
    Wear protective gloves/protective clothing/eye protection/face protection.
    In case of fire: Use for extinction: CO2, powder or water spray.
    Store in a well-ventilated place.
    Keep cool.
    Dispose of contents/container in accordance with local/regional/national/international regulations.

    Warning

    SDS & Safety Documents

  • Description & Specifications
  • Safety and Handling

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