Diisobutylaluminium hydride, 1.0M solution in heptane, AcroSeal™, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals 201058000

Catalog No. AC201058000

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Lewis acid, Reduction reagent

Specifications

• Chemical Name or Material: Diisobutylaluminium hydride
• Name Note: 1.0M Solution in Heptane
• Melting Point: -70.0°C
• Linear Formula: [(CH₃)₂CHCH₂]₂AIH
• Beilstein: 04, IV, 4400
• Fieser: 01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
• Merck Index: 15, 3212
• Solubility Information: Solubility in water: vigorous reaction. Other solubilities: miscible with saturated aliphatic and aromatic, hydrocarbons
• Packaging: AcroSeal™ Glass Bottle
• Quantity: 800 mL
• Physical Form: Solution

• Color: Undesignated
• CAS: 1191-15-7, 142-82-5
• Molecular Formula: C₈H₁₉Al
• MDL Number: MFCD00008928
• Concentration: 19.5 to 20.5% (DIBAL-H, on Al basis)
• Density: 0.7000g/mL
• Synonym: DIBAL-H, 1.0M solution in heptane
• Formula Weight: 142.22
• Specific Gravity: 0.7
• Flash Point: −1°C

Safety and Handling

GHS H Statement:
Causes severe skin burns and eye damage.
May be fatal if swallowed and enters airways.
May cause drowsiness or dizziness.
Very toxic to aquatic life with long lasting effects.
In contact with water releases flammable gases which may ignite spontaneously.

GHS P Statement:
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
Wear eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Avoid breathing dust/fume/gas/mist/vapors/spray.
IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
Do NOT induce vomiting.
Avoid release to the environment.
Store in a dry place. Store in a closed container.

WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.

Danger

RUO – Research Use Only