Alfa Aesar™ Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF

Manufacturer: Alfa Aesar™ H51156AE

Quantity 100mL

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Catalog No. AAH51156AE

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    Chemical Identifiers

    CAS 807329-97-1
    Molecular Formula C3H7ClMg·LiCl
    Linear Formula (CH3)2CHMgCl·LiCl
    Formula Weight 145.24g/mol
    MDL Number MFCD07784514
    UN Number UN3399
    Chemical Name or Material Isopropylmagnesium chloride - LiCl complex

    Specifications

    Quantity 100mL,100mL
    Concentration 1M in MeTHF
    Flash Point −17°C (1.4°F)
    CAS 807329-97-1
    Molecular Formula C3H7ClMg·LiCl
    Linear Formula (CH3)2CHMgCl·LiCl
    Formula Weight 145.24g/mol
    MDL Number MFCD07784514
    UN Number UN3399
    Health Hazard 1 Danger
    Health Hazard 2 GHS H Statement
    H225-H261-H314-H318
    Highly flammable liquid and vapor.
    In contact with water releases flammable gas.
    Causes severe skin burns and eye damage.
    Causes serious eye damage.
    Health Hazard 3 GHS P Statement
    P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
    Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
    Handle under inert gas.
    Protect from moisture.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.
    DOT Information Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
    Chemical Name or Material Isopropylmagnesium chloride - LiCl complex

    Description

    Applications
    Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

    Solubility
    Miscible with ethers and amines.

    Notes
    Air and moisture sensitive. Incompatible with oxidizing agents and water.

    GHS H Statement
    H225-H261-H314-H318
    Highly flammable liquid and vapor.
    In contact with water releases flammable gas.
    Causes severe skin burns and eye damage.
    Causes serious eye damage.

    GHS P Statement
    P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
    Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
    Handle under inert gas.
    Protect from moisture.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.

    Danger

    SDS & Safety Documents

  • Description & Specifications
  • Safety and Handling

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