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Methyl dichloroacetate, 99%, Thermo Scientific Chemicals
Description
Methyl dichloroacetate may be used in the diastereoselctive synthesis of bicyclic chlorocyclopropane, as difunctional initiator during atom transfer radical polymerization of methyl or n-butyl acrylate, as reagent during CrCl2-induced olefination of aldehydes. It is a reactant involved in nucleophilic substitution reactions with nitro(pentafluorosulfanyl)benzenes, azide-alkyl halide cycloaddition and atom transfer radical addition, Chemical modification of STn antigen for enhancement of synthetic carbohydrate vaccines, three component reaction of arynes with cyclic ethers and active methines, catalytic radical haloalkylation for synthesis of neodysidenin and addition reactions for syntehsis of enantiopure 3,4-diamino esters or amides.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Methyl dichloroacetate may be used in the diastereoselctive synthesis of bicyclic chlorocyclopropane, as difunctional initiator during atom transfer radical polymerization of methyl or n-butyl acrylate, as reagent during CrCl2-induced olefination of aldehydes. It is a reactant involved in nucleophilic substitution reactions with nitro(pentafluorosulfanyl)benzenes, azide-alkyl halide cycloaddition and atom transfer radical addition, Chemical modification of STn antigen for enhancement of synthetic carbohydrate vaccines, three component reaction of arynes with cyclic ethers and active methines, catalytic radical haloalkylation for synthesis of neodysidenin and addition reactions for syntehsis of enantiopure 3,4-diamino esters or amides.
Solubility
Soluble in water. (4 g/L).
Notes
Store at room temperature. Incompatible with oxidizing agents. Ensure proper ventilation.
Specifications
Melting Point | -52°C |
Density | 1.38 |
Boiling Point | 142°C to 144°C |
Flash Point | 70°C (158°F) |
Odor | Pungent |
Refractive Index | 1.442 |
Linear Formula | Cl2CHCO2CH3 |
Quantity | 100 g |
UN Number | UN2299 |
Solubility Information | Soluble in water. (4g/L). |
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Safety and Handling
Hazard Category | H227-H315-H319-H335 |
Hazard Statement | GHS H Statement H331-H227-H315-H319-H335 Toxic if inhaled. Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. |
Precautionary Statement | P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c |
DOTInformation | Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: METHYL DICHLOROACETATE |
EINECSNumber | 204-146-8 |
RTECSNumber | AG6625000 |
TSCA | Yes |
Recommended Storage | Ambient temperatures |
RUO – Research Use Only
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