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Alfa Aesar™ Propargyl bromide, 80% in toluene, stab. with MgO

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Quantity:
50mL
250mL
1000mL
106-96-7
C3H3Br
118.961
MFCD00000241
YORCIIVHUBAYBQ-UHFFFAOYSA-N
propargyl bromide,3-bromopropyne,3-bromo-1-propyne,1-propyne, 3-bromo,2-propynyl bromide,propynyl bromide,1-bromo-2-propyne,propyne, 3-bromo,gamma-bromoallylene,1-brom-2-propin
7842
3-bromoprop-1-yne
C#CCBr
106-96-7
C3H3Br
118.961
MFCD00000241
YORCIIVHUBAYBQ-UHFFFAOYSA-N
propargyl bromide,3-bromopropyne,3-bromo-1-propyne,1-propyne, 3-bromo,2-propynyl bromide,propynyl bromide,1-bromo-2-propyne,propyne, 3-bromo,gamma-bromoallylene,1-brom-2-propin
7842
3-bromoprop-1-yne
C#CCBr
Applications
Propargyl bromide, 80% in toluene is used to prepare betulonic acid-peptide conjugates with anti-inflammatory activity and propargylic amines employed in enyne metathesis. It finds application in the propargylation of spiro ketones, allylic alcohols and enone complexes. In Barbier-type reaction, it reacts with aldehydes to give alkyne alcohols. It is actively involved in the synthesis of polyethylene glycol (PEG) and peptide-grafted polyesters.

Solubility
Miscible with ethanol, ether, benzene, carbon tetrachloride and chloroform. Immiscible with water.

Notes
Light sensitive. Store in a cool place. Incompatible withbases, strong oxidizing agents, copper, peroxides, silver, silver oxides, mercury and mercury oxides.
Density 1.335
Sensitivity Light sensitive
Refractive Index 1.494
Quantity 50mL
Boiling Point 88°C to 90°C
Flash Point 3°C (37°F)
Melting Point -61°C
UN Number UN2924
Beilstein 605309
Concentration or Composition (by Analyte or Components) 80% in toluene
Solubility Information Miscible with ethanol,ether,benzene,carbon tetrachloride and chloroform. Immiscible with water.
Formula Weight 118.97
Chemical Name or Material Propargyl bromide, stabilized with MgO
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GHS H Statement
H225-H300-H304-H361-H373-H314-H335-H336
Highly flammable liquid and vapour.
Fatal if swallowed.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
May cause drowsiness or dizziness.

P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H225-H301-H304-H314-H335-H336-H361-H373

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

EINECSNumber : 203-447-1

RTECSNumber : UK4375000

TSCA : Yes

Recommended Storage : Keep cold