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SiliCycle™ SiliaBond™ Functionalized Silica Gels, Pyridinium Chlorochromate (PCC), 40 to 63 μm, 60 Å

Powerful oxidizing agent that minimizes side reactions, greatly facilitates removal of Cr byproducts and is compatible with acid-sensitive protecting groups.

$68.10 - $3260.00

Specifications

For Use With (Application) Removal of Polymeric Reduced Chromium By-products
Particle Size 40 to 63 μm
Product Type Bulk Functionalized Irregular Silica Gel
Particle Shape Irregular
Pore Size 60 Å
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Products 8
Catalog Number Mfr. No. Quantity Price Quantity & Availability  
Catalog Number Mfr. No. Quantity Price Quantity & Availability  
01-184-423
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SiliCycle™
R24030B10G
10 g
Each for $68.10
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01-184-357
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SiliCycle™
R24030B25G
25 g
Each for $141.80
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01-184-358
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SiliCycle™
R24030B50G
50 g
Each for $256.50
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01-184-359
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SiliCycle™
R24030B100G
100 g
Each for $408.00
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01-184-360
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SiliCycle™
R24030B250G
250 g
Each for $957.00
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01-184-424
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SiliCycle™
R24030B500G
500 g
Each for $1,805.00
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01-184-361
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SiliCycle™
R24030B1KG
1 kg
Each for $3,260.00
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01-184-356
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SiliCycle™
R24030B5G
5 g Item Discontinued This item has been discontinued by the supplier. Please to view product availability in your area. N/A
Description

Description

SiliaBond™ Pyridinium Chlorochromate (Si-PCC) is used for the general oxidation of alcohols to carbonyl compounds, selective oxidation of allylic and benzylic alcohols, organometallic oxidation, oxidative transpositions, oxidative cleavages, allylic and benzylic oxidation, and oxidative cyclizations.

Using PCC immobilized onto silica gel provides anhydrous conditions that may otherwise promote side reactions and reduce yields. It greatly facilitates the removal of polymeric-reduced chromium byproducts and is compatible with acid-sensitive protecting groups. When used in conjunction with ultrasounds, kinetics are increased and the amount of oxidant required to complete the reaction is decreased.

Oxidation of 4-tert-butylcyclohexanol to 4-tert-butylcyclohexanone with 2 eq. in anhydrous DCM at room temperature is complete after 6 hours.

Specifications

Specifications

Removal of Polymeric Reduced Chromium By-products
Bulk Functionalized Irregular Silica Gel
60 Å
Pyridinium Chlorochromate (PCC)
40 to 63 μm
Irregular
SiliaBond™
SDS
Documents

Documents

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