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SiliCycle™ SiliaBond™ Functionalized Silica Gels, Pyridinium Dichromate (PDC), 40 to 63 μm, 60 Å
Our Pyridinium Dichromate (Si-PDC) may be used as an alternative to Si-PCC in nucleoside and carbohydrate oxidation.
$39.90 - $3020.00
Specifications
| For Use With (Application) | Oxidizing Allylic and Benzylic Alcohols, Saturated Primary and Secondary Alcohols |
|---|---|
| Particle Size | 40 to 63 μm |
| Product Type | Bulk Functionalized Irregular Silica Gel |
| Particle Shape | Irregular |
| Pore Size | 60 Å |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity & Availability | |||||
|
01-184-362
|
SiliCycle™
R24530B5G |
5 g |
Each for $39.90
|
|
01-184-363
|
SiliCycle™
R24530B10G |
10 g |
Each for $63.00
|
|
01-184-364
|
SiliCycle™
R24530B25G |
25 g |
Each for $130.20
|
|
01-184-365
|
SiliCycle™
R24530B50G |
50 g |
Each for $236.50
|
|
01-184-425
|
SiliCycle™
R24530B100G |
100 g |
Each for $377.00
|
|
01-184-366
|
SiliCycle™
R24530B250G |
250 g |
Each for $884.50
|
|
01-184-367
|
SiliCycle™
R24530B500G |
500 g |
Each for $1,670.00
|
|
01-184-368
|
SiliCycle™
R24530B1KG |
1 kg |
Each for $3,020.00
|
|
Description
SiliaBond™ Pyridinium Dichromate (Si-PDC) may be used as an alternative to Si-PCC in nucleoside and carbohydrate oxidation, particularly for fragile molecules. SiliaBond™ PDC can also be used in conjunction with tertbutylhydroperoxide for a variety of oxidative transformations.
PDC immobilized onto silica is a very convenient and effective reagent for oxidizing allylic and benzylic alcohols, saturated primary and secondary alcohols, and is compatible with acid-sensitive groups, such as cyclopropane ring or ketal function.
Oxidation of 4-tert-butylcyclohexanol to 4-tert-butylcyclohexanone with 2 eq. of Si-PDC in anhydrous DCM at room temperature is complete after 6 hours.
Specifications
| Oxidizing Allylic and Benzylic Alcohols, Saturated Primary and Secondary Alcohols | |
| Bulk Functionalized Irregular Silica Gel | |
| 60 Å | |
| Pyridinium Dichromate (PDC) |
| 40 to 63 μm | |
| Irregular | |
| SiliaBond™ |
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