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CAS RN 67719-69-1

CH3AlCH3H2CHCHCClTi

CAS RN 67719-69-1

IUPAC Name: titanium(4+) (dimethylalumanyl)methanide bis(cyclopenta-2,4-dien-1-ide) chloride
Synonyms: tebbe's reagent
Molecular Weight (g/mol): 284.59
Molecular Formula: C13H18AlClTi
InChi Key: HIVIAXIRSNAVAD-UHFFFAOYSA-M
SMILES: [Cl-].[Ti+4].C[Al](C)[CH2-].[CH-]1C=CC=C1.[CH-]1C=CC=C1
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1

Tebbe reagent, 0.5M solution in toluene

CAS: 67719-69-1 | C13H18AlClTi

Color Purple to Red
Physical Form Solution
Chemical Name or Material Tebbe reagent
Density 0.9270g/mL
Name Note 0.5M solution in toluene
Fieser 08,83; 10,87; 11,52; 12,54; 13,71; 15,79; 16,70; 17,69
CAS 108-88-3
Health Hazard 3 GHS P Statement
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Use personal protective equipment as required. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not breathe dust/fume/gas/mist/vapors/spray. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment.
MDL Number MFCD00151575
Health Hazard 2 GHS H Statement
Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Highly flammable liquid and vapor.
Solubility Information Solubility in water: reacts.
Flash Point 4°C
Health Hazard 1 Danger
Synonym Bis(cyclopentadienyl-μ-chloro(dimethylaluminum-μ-methylenetitanium
Molecular Formula C13H18AlClTi
Formula Weight 284.62
Specific Gravity 0.927
2

mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene

CAS: 67719-69-1 Molecular Formula: C13H18AlClTi MDL Number: MFCD00151575 Synonym: Tebbe Reagent

CAS 67719-69-1
MDL Number MFCD00151575
Synonym Tebbe Reagent
Molecular Formula C13H18AlClTi
3

Tebbe reagent, 0.5M solution in toluene, AcroSeal™

CAS: 67719-69-1 Molecular Formula: C13H18AlClTi MDL Number: MFCD00151575 Synonym: Bis(cyclopentadienyl-micron-chloro(dimethylaluminum-micron-methylenetitanium

CAS 67719-69-1
MDL Number MFCD00151575
Synonym Bis(cyclopentadienyl-micron-chloro(dimethylaluminum-micron-methylenetitanium
Molecular Formula C13H18AlClTi
4

Sigma Aldrich Tebbe Reagent Solution

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

ENCOMPASS
Linear Formula C13H18AlClTi
CAS 67719-69-1
Biological Activity Central Nervous System
Molecular Weight (g/mol) 284.58 g/mol
MDL Number MFCD00151575
Health Hazard 1 UN 2924 8(3) / PGII
Synonym Bis(cyclopentadienyl)-mu-chloro-f(dimethylaluminum)-mu-methylenetitanium
Recommended Storage Room Temperature
Molecular Formula C13H18AlClTi
Density 0.927 g/mL at 25°C