Grignard Reagents

Alfa Aesar™ Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles

Chemical Name or Material: Phenylmagnesium bromide CAS: 100-58-3 Formula Weight: 181.31 MDL Number: MFCD00000038 UN Number: UN3399

n-Butylethylmagnesium, 0.9M Solution in Heptane, AcroSeal™, ACROS Organics™ Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: n-Butylethylmagnesium Name Note: 0.9M Solution in Heptane CAS: 62202-86-2 CAS: 142-82-5 Molecular Formula: C6H14Mg Linear Formula: CH3CH2Mg(CH2)3CH3 Formula Weight: 110.48 MDL Number: MFCD00072569

Allylmagnesium bromide, 1M solution in diethyl ether, AcroSeal™, ACROS Organics™

Chemical Name or Material: Allylmagnesium bromide Name Note: 1M solution in diethyl ether CAS: 1730-25-2 CAS Min %: 15.37 CAS Max %: 18.78 CAS: 60-29-7 CAS Min %: 81.22 CAS Max %: 84.64 Molecular Formula: C3H5BrMg Linear Formula: H2C=CHCH2MgBr Formula Weight: 145.28 MDL Number: MFCD00000044

2-Methyl-1-propenylmagnesium bromide, 0.5M solution in THF, AcroSeal™, ACROS Organics™ Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: 2-Methyl-1-propenylmagnesium bromide CAS: 38614-36-7 CAS Min %: 7.53 CAS Max %: 9.2 CAS: 109-99-9 CAS Min %: 90.8 CAS Max %: 92.47 Molecular Formula: C4H7BrMg Formula Weight: 159.31

3,4-(Methylenedioxy)phenylmagnesium bromide, 0.8M solution in toluene/THF (50:50), AcroSeal™, ACROS Organics™ Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: 3, 4-(Methylenedioxy)phenylmagnesium bromide CAS: 17680-04-5 CAS Min %: 15.17 CAS Max %: 19.5 CAS: 109-99-9 CAS Min %: 80.5 CAS Max %: 84.83 CAS: 108-88-3 Molecular Formula: C7H5BrMgO2 Formula Weight: 225.32

5-Fluoro-2-methoxyphenylmagnesium bromide, 0.5M solution in THF, AcroSeal™, ACROS Organics™

Chemical Name or Material: 5-Fluoro-2-methoxyphenylmagnesium bromide CAS: 188132-02-7 CAS Min %: 9.68 CAS Max %: 14.51 CAS: 109-99-9 CAS Min %: 85.49 CAS Max %: 90.32 Molecular Formula: C7H6BrFMgO Linear Formula: F(OCH3)C6H3MgBr Formula Weight: 229.33 MDL Number: MFCD01311481

Phenylmagnesium bromide, Acros Organics Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: Phenylmagnesium bromide CAS: 100-58-3 CAS: 5614-37-9 Molecular Formula: C6H5BrMg Formula Weight: 181.31

1-Propynylmagnesium bromide, 0.5M solution in THF, AcroSeal™, ACROS Organics™

Chemical Name or Material: 1-Propynylmagnesium bromide CAS: 16466-97-0 CAS: 109-99-9 Molecular Formula: C3H3BrMg Formula Weight: 143.26 MDL Number: MFCD00216588

2-Methyl-2-phenylpropylmagnesium chloride, 0.5M solution in diethyleether, AcroSeal™, ACROS Organics™ Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: 2-Methyl-2-phenylpropylmagnesium chloride CAS: 35293-35-7 CAS Min %: 10.16 CAS Max %: 15.23 CAS: 60-29-7 CAS Min %: 84.77 CAS Max %: 89.84 Molecular Formula: C10H13ClMg Linear Formula: C6H5C(CH3)2CH2MgCl Formula Weight: 192.97

Cyclohexylmagnesium chloride, 1.3M solution in THF/Toluene, AcroSeal™, ACROS Organics™

Chemical Name or Material: Cyclohexylmagnesium chloride CAS: 931-51-1 CAS: 109-99-9 CAS: 108-88-3 Molecular Formula: C6H11ClMg Linear Formula: (C6H11)MgCl Formula Weight: 142.91 MDL Number: MFCD00003816

Alfa Aesar™ Methylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles

Chemical Name or Material: Methylmagnesium bromide CAS: 75-16-1 Linear Formula: CH3MgBr Formula Weight: 119.26 MDL Number: MFCD00000041 UN Number: UN1928

Alfa Aesar™ 3-Chlorophenylmagnesium bromide, 1M in MeTHF

Chemical Name or Material: 3-Chlorophenylmagnesium bromide CAS: 36229-42-2 Molecular Formula: C6H4BrClMg Formula Weight: 215.76 MDL Number: MFCD00672003 UN Number: UN2924

Methylmagnesium bromide, 3.2M solution in 2-Methyl-THF, AcroSeal™, ACROS Organics™ Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: Methylmagnesium bromide CAS: 75-16-1 CAS: 96-47-9 Molecular Formula: CH3BrMg Linear Formula: CH3MgBr Formula Weight: 119.24

Alfa Aesar™ Phenylmagnesium bromide, 3M in ether

Chemical Name or Material: Phenylmagnesium bromide CAS: 100-58-3 Formula Weight: 181.31 MDL Number: MFCD00000038 UN Number: UN3399

Ethylmagnesium bromide, 3M in diethyl ether, AcroSeal™, ACROS Organics™

Chemical Name or Material: Ethylmagnesium bromide CAS: 925-90-6 CAS: 60-29-7 Molecular Formula: C2H5BrMg Linear Formula: C2H5MgBr Formula Weight: 133.27 MDL Number: MFCD00000043

Alfa Aesar™ Allylmagnesium chloride, 1M in MeTHF

Chemical Name or Material: Allylmagnesium chloride CAS: 2622-05-1 Molecular Formula: C3H5ClMg Linear Formula: CH2=CHCH2MgCl Formula Weight: 100.83 MDL Number: MFCD00000473 UN Number: UN3399

tert-Butylmagnesium chloride , 1,7M solution in diethyl ether , ACROS Organics™ Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: tert-Butylmagnesium chloride CAS: 677-22-5 CAS: 60-29-7 Molecular Formula: C4H9ClMg Linear Formula: (CH3)3CMgCl Formula Weight: 116.87 MDL Number: MFCD00000465

3,5-Bis(trifluoromethyl)phenylmagnesium bromide, 0.5M solution in THF, ACROS Organics™

Chemical Name or Material: 3, 5-Bis(trifluoromethyl)phenylmagnesium bromide CAS: 112981-69-8 CAS Min %: 12.51 CAS Max %: 18.76 CAS: 109-99-9 CAS Min %: 81.24 CAS Max %: 87.5 Molecular Formula: C8H3BrF6Mg Linear Formula: BrMgC6H3(CF3)2 Formula Weight: 317.31 MDL Number: MFCD07369723

p-Tolylmagnesium bromide, Acros Organics

Chemical Name or Material: p-Tolylmagnesium bromide CAS: 4294-57-9 CAS: 60-29-7 Molecular Formula: C7H7BrMg Formula Weight: 195.34

Pentafluorophenylmagnesium bromide, Acros Organics Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: Pentafluorophenylmagnesium bromide CAS: 879-05-0 CAS: 60-29-7 Molecular Formula: C6BrF5Mg Formula Weight: 271.27

4-Methoxyphenylmagnesium bromide, 1M solution in THF, ACROS Organics™ Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: 4-Methoxyphenylmagnesium bromide CAS: 13139-86-1 CAS Min %: 19.02 CAS Max %: 25.36 CAS: 109-99-9 CAS Min %: 74.64 CAS Max %: 80.98 Molecular Formula: C7H7BrMgO Linear Formula: CH3O(C6H4)MgBr Formula Weight: 211.34 MDL Number: MFCD00013515

Isopropylmagnesium bromide, 3M solution in 2-Methyltetrahydrofuran, ACROS Organics™

Chemical Name or Material: Isopropylmagnesium bromide Name Note: 3M solution in 2-Methyltetrahydrofuran CAS: 920-39-8 CAS: 96-47-9 Molecular Formula: C3H7BrMg Linear Formula: (CH3)2CHMgBr Formula Weight: 147.31 MDL Number: MFCD00672110

Di-n-butylmagnesium, ACROS Organics™

Chemical Name or Material: Di-n-butylmagnesium CAS: 1191-47-5 CAS: 142-82-5 CAS: 97-93-8 Molecular Formula: C8H18Mg Linear Formula: (C4H9)2Mg Formula Weight: 138.54 MDL Number: MFCD00015225

Alfa Aesar™ Methylmagnesium bromide, 3M in ether

Chemical Name or Material: Methylmagnesium bromide CAS: 75-16-1 Linear Formula: CH3MgBr Formula Weight: 119.26 MDL Number: MFCD00000041 UN Number: UN1928

(1,3-Dioxolan-2-ylmethyl)magnesium bromide, 0.5M solution in THF, AcroSeal™, ACROS Organics™ Available on GSA/VA Contract for Federal Government customers only.

Chemical Name or Material: (1, 3-Dioxolan-2-ylmethyl)magnesium bromide CAS: 180675-22-3 CAS Min %: 8.14 CAS Max %: 12.21 CAS: 109-99-9 CAS Min %: 87.79 CAS Max %: 91.86 Molecular Formula: C4H7BrMgO2 Formula Weight: 191.31

Pentamethylenebis(magnesium bromide), 0.5M solution in THF, AcroSeal™, ACROS Organics™

Chemical Name or Material: Pentamethylenebis(magnesium bromide) CAS: 23708-48-7 CAS: 109-99-9 Molecular Formula: C5H10Br2Mg2 Formula Weight: 278.55 Synonym: Pentane-1, 5-di(magnesium bromide)

Alfa Aesar™ 2-Naphthylmagnesium bromide, 0.25M in MeTHF

Chemical Name or Material: 2-Naphthylmagnesium bromide CAS: 21473-01-8 Molecular Formula: C10H7BrMg Formula Weight: 231.37 MDL Number: MFCD01319910 UN Number: UN2924

Alfa Aesar™ Cyclohexylmagnesium chloride, 1M in MeTHF

Chemical Name or Material: Cyclohexylmagnesium chloride CAS: 931-51-1 Molecular Formula: C6H11ClMg Formula Weight: 142.91 MDL Number: MFCD00003816 UN Number: UN2924

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