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Organosulfur compounds that contain a thiocyanate functional group, or thiocyanate ion; thiocyanate consists of a sulfur atom bonded to a carbon atom that is bonded to a nitrogen atom in a triple bond (cyanide functional group).
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Potassium thiocyanate is an inorganic potassium salt. Phase transitions in potassium thiocyanate (KSCN) have been investigated by X-ray diffraction studies. The order-disorder type transition with respect to the orientation of the thiocyanate ions was identified. Its polarized infrared spectrum has been reported. It participates in the ring-opening of aziridines. The reaction was carried out in the presence of sulfated zirconia to afford the corresponding -aminothiocyanates.
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