1,1'-(Azodicarbonyl)dipiperidine, 97%, Thermo Scientific Chemicals

Description

CAS: 10465-81-3 | C12H20N4O2 | 252.32 g/mol

It is used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides. It is widely used reagent for the Mitsunobu reaction. It is reactant for preparation of polyfluoroalkylated tripyrazolylmethane ligands, (-)-Hygromycin A via Mitsunobu glycosylation, optically active α,α-disubstituted amino acids via Mitsunobu reaction, aza-β-lactams through [2+2] cycloaddition reactions, glycosyl disulfides, pyridine ether PPAR agonists, S-glycosyl amino acid, building blocks for combinatorial neoglycopeptide synthesis and is a histamine H3 receptor antagonists. It is a reactant for Mitsunobu inversion reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides. It is widely used reagent for the Mitsunobu reaction. It is reactant for preparation of polyfluoroalkylated tripyrazolylmethane ligands, (-)-Hygromycin A via Mitsunobu glycosylation, optically active α,α-disubstituted amino acids via Mitsunobu reaction, aza-β-lactams through [2+2] cycloaddition reactions, glycosyl disulfides, pyridine ether PPAR agonists, S-glycosyl amino acid, building blocks for combinatorial neoglycopeptide synthesis and is a histamine H3 receptor antagonists. It is a reactant for Mitsunobu inversion reactions.

Solubility
Slightly soluble in water.

Notes
Store in cool dry conditions. Incompatible with oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 10465-81-3
• Molecular Formula: C12H20N4O2
• Molecular Weight (g/mol): 252.32
• MDL Number: MFCD00010111
• InChI Key: OQJBFFCUFALWQL-UHFFFAOYSA-N
• Synonym: 1,1'-azodicarbonyl-dipiperidine, 1,1-azodicarbonyl dipiperidine, 1,1'-azodicarbonyl dipiperidine, addp, diazene-1,2-diylbis piperidin-1-ylmethanone, azodicarboxylic acid dipiperidine, ne-n-piperidine-1-carbonylimino piperidine-1-carboxamide, 1,1'-azodicarbonyl dipiperidine addp, piperidyl piperidylcarbonyl diazenyl ketone, e-diazene-1,2-diylbis piperidin-1-ylmethanone
• PubChem CID: 5702657
• IUPAC Name: (NE)-N-(piperidine-1-carbonylimino)piperidine-1-carboxamide
• SMILES: O=C(N=NC(=O)N1CCCCC1)N1CCCCC1

• Melting Point: 133°C to 136°C
• Odor: Odorless
• Quantity: 25 g
• Solubility Information: Slightly soluble in water.
• Formula Weight: 252.32
• Percent Purity: 97%
• Chemical Name or Material: 1,1'-(Azodicarbonyl)dipiperidine

Safety and Handling

Hazard Category	H315-H319-H335
Hazard Statement	GHS H Statement H315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
TSCA	No
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only