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1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%, Thermo Scientific Chemicals

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Quantity:
250mg
64536-78-3
C31H50F6IrNP2
804.90
MFCD00075097
WLRQNTYCIFESRH-UHFFFAOYSA-N
crabtree's catalyst, unii-816rs2nbpn, 816rs2nbpn, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium hexafluorophosphate, iridium i hexafluorophosphate, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium i hexafluorophosphate, tricyclohexylphosphine 1,5-cyclooctadiene pyridine iridium i hexafluorophosphate, felkin-crabtree catalyst, crabtree's catalyst mi, crabtree's catalyst hexafluorophosphate
5702647
(1Z,5Z)-cycloocta-1,5-diene;iridium;pyridine;tricyclohexylphosphane;hexafluorophosphate
[Ir].C1=CC=NC=C1.F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.C1CCC(CC1)P(C1CCCCC1)C1CCCCC1
64536-78-3
C31H50F6IrNP2
804.90
MFCD00075097
WLRQNTYCIFESRH-UHFFFAOYSA-N
crabtree's catalyst, unii-816rs2nbpn, 816rs2nbpn, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium hexafluorophosphate, iridium i hexafluorophosphate, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium i hexafluorophosphate, tricyclohexylphosphine 1,5-cyclooctadiene pyridine iridium i hexafluorophosphate, felkin-crabtree catalyst, crabtree's catalyst mi, crabtree's catalyst hexafluorophosphate
5702647
(1Z,5Z)-cycloocta-1,5-diene;iridium;pyridine;tricyclohexylphosphane;hexafluorophosphate
[Ir].C1=CC=NC=C1.F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.C1CCC(CC1)P(C1CCCCC1)C1CCCCC1

Description

 

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Melting Point 175°C (decomposition)
Quantity 250mg
Solubility Information Slightly soluble in acetone,dichloromethane,ethanol and diethyl ether; Insoluble in water.
Sensitivity Moisture sensitive
Formula Weight 804.89
Physical Form Orange crystalline powder
Percent Purity 99%
Chemical Name or Material 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate

Safety and Handling

GHS H Statement
H315-H319
Causes skin irritation.
Causes serious eye irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

TSCA : No

Recommended Storage : Ambient temperatures

SDS

RUO – Research Use Only