1-Methylpiperidine, 99%

Description

CAS: 626-67-5 | C6H14ClN | 135.64 g/mol

1-Methylpiperidine is a reactant for sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines, One-pot synthesis of Z-cinnamic acids. It is used in the synthesis of Unsymmetrical ureas, Antibacterial imidazolium, pyrrolidinium, and piperidinium salts, C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Methylpiperidine is a reactant for sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines, One-pot synthesis of Z-cinnamic acids. It is used in the synthesis of Unsymmetrical ureas, Antibacterial imidazolium, pyrrolidinium, and piperidinium salts, C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling.

Solubility
Fully miscible in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with.acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents, Carbon dioxide.

Specifications

Chemical Identifiers

• CAS: 626-67-5
• Molecular Formula: C6H14ClN
• Molecular Weight (g/mol): 135.64
• MDL Number: MFCD00006491
• InChI Key: QDUXDCXILAPLAG-UHFFFAOYSA-N
• Synonym: n-methylpiperidine, piperidine, 1-methyl, methylpiperidine, n-methyl piperidine, 1-methyl-piperidine, n-methylpiperidin, methylpiperdine, 1-methylpiperadine, n-methyl-piperidine, 1-methyl piperidine
• PubChem CID: 12291
• IUPAC Name: 1-methylpiperidine
• SMILES: [H+].[Cl-].CN1CCCCC1

• Melting Point: -50°C
• Density: 0.816
• pH: 12
• Boiling Point: 105°C to 107°C
• Flash Point: 3°C (37°F)
• Odor: Amine-like
• Refractive Index: 1.4378
• Quantity: 10 g
• UN Number: UN2399
• Beilstein: 1073
• Solubility Information: Fully miscible in water.
• Formula Weight: 99.18
• Percent Purity: 99%
• Chemical Name or Material: 1-Methylpiperidine

Safety and Handling

Hazard Category	H225-H302+H312+H332-H314-H335
Hazard Statement	GHS H Statement H225-H331-H314-H318-H302 Highly flammable liquid and vapor. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.
Precautionary Statement	P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: 1-METHYLPIPERIDINE
EINECSNumber	210-959-9
RTECSNumber	TN1225000
TSCA	Yes
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only