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  6. Sigma Aldrich 1-Phenyl-1-trimethylsiloxyethylene

Sigma Aldrich 1-Phenyl-1-trimethylsiloxyethylene

Catalog No. 23504025G Shop All MilliporeSigma Sigma Organic Chemistry Products
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

  • 1-phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. it also undergoes mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.1-phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
  • α-amino ketones in water via mannich-type reaction
  • Cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction

Specifications

CAS 13735-81-4
Density 0.938 g/mL (at 25°C (literature))
Boiling Point 88°C to 89°C (11 mmHg)
Molecular Formula C11H16OSi
Refractive Index n20/D 1.502 (literature)
Linear Formula C6H5C(=CH2)OSi(CH3)3
MDL Number MFCD00008582
Quantity 25 g
Synonym alpha-(Trimethylsiloxy)styrene; Acetophenone enol trimethylsilyl ether
Molecular Weight (g/mol) 192.33
Percent Purity 98%
Biological Activity Respiratory System
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