1-Phenyl-1-trimethylsiloxyethylene, 95%

Description

CAS: 13735-81-4 | C11H16OSi | 192.333 g/mol

1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.

Solubility
Reacts with water.

Notes
Store at 4°C. Moisture Sensitive. Store under inert gas. Incompatible materials are Oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 13735-81-4
• Molecular Formula: C11H16OSi
• Molecular Weight (g/mol): 192.333
• MDL Number: MFCD00008582
• InChI Key: AFFPCIMDERUIST-UHFFFAOYSA-N
• Synonym: 1-phenyl-1-trimethylsiloxyethylene, trimethyl 1-phenylvinyl oxy silane, 1-phenyl-1-trimethylsilyloxyethylene, 1-phenyl-1-trimethylsiloxy ethylene, 1-phenyl-1-trimethylsilyloxy ethylene, benzene, 1-trimethylsilyl oxy ethenyl, silane, trimethyl 1-phenylethenyl oxy, acmc-209ccf
• PubChem CID: 117406
• IUPAC Name: trimethyl(1-phenylethenoxy)silane
• SMILES: C[Si](C)(C)OC(=C)C1=CC=CC=C1

• Boiling Point: 53°C to 54°C (1mmHg)
• Quantity: 1 g
• Beilstein: 1306914
• Flash Point: 78°C (172°F)
• Solubility Information: Reacts with water.
• Formula Weight: 192.34
• Percent Purity: 97%
• Refractive Index: 1.502
• Sensitivity: Moisture sensitive
• Density: 0.938
• Chemical Name or Material: 1-Phenyl-1-trimethylsiloxyethylene

Safety and Handling

Hazard Category	H227-H315-H319-H335
Hazard Statement	GHS H Statement H315-H319-H335-H227 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.
Precautionary Statement	P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
EINECSNumber	237-308-1
TSCA	Yes
Recommended Storage	Keep cold; Store under Nitrogen

SDS

RUO – Research Use Only