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  8. (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine

(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine

Catalog No. AAH2700614
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AAH2700603 1 g
AAH2700606 5 g
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Catalog No. AAH2700614 Supplier Thermo Scientific Chemicals Supplier No. H2700614
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Description

CAS: 167316-27-0 | C21H23N2O2S | 367.49 g/mol

Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.

Solubility
Solubility in hot Acetonitrile (almost transparency).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 167316-27-0
Molecular Formula C21H23N2O2S
Molecular Weight (g/mol) 367.49
MDL Number MFCD03095684
InChI Key UOPFIWYXBIHPIP-SFTDATJTSA-O
Synonym 1s,2s-+-n-p-tosyl-1,2-diphenylethylenediamine, s,s-tsdpen, 1s,2s-+-n-4-toluenesulfonyl-1,2-diphenylethylenediamine, 1s,2s-n-4-toluenesulfonyl-1,2-diphenylethylene-1,2-diamine, 1s,2s---n-p-tosyl-1,2-diphenylethylenediamine, n-1s,2s-2-amino-1,2-diphenylethyl-4-methylbenzenesulfonamide, 1s, 2s-+-n-4-toluene sulfonyl 1,2-diphenyl-1,2-ethane diamine, s,s-n-p-toluenesulfonyl-1,2-diphenylethylenediamine, 1s,2s-tsdpen, s,s-n-2-amino-1,2-diphenylethyl-p-toluenesulfonamide
PubChem CID 6612782
IUPAC Name N-[(1S,2S)-2-amino-1,2-diphenylethyl]-4-methylbenzenesulfonamide
SMILES CC1=CC=C(C=C1)S(=O)(=O)N[C@H]([C@@H]([NH3+])C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 127°C to 130°C
Quantity 25 g
Optical Rotation +29° (c=1 in Chloroform)
Formula Weight 366.48
Chemical Name or Material (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine

Safety and Handling

Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
TSCA No
Recommended Storage Ambient temperatures
SDS

RUO – Research Use Only

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