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2,4'-Dibromoacetophenone, 98+%

Catalog No. AAA1368714
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Quantity:
25 g
100 g

CAS: 99-73-0 | C8H6Br2O | 277.943 g/mol

2,4'-Dibromoacetophenone is used as a reagent for analysis of fatty acids by HPLC as 4-bromophenacyl esters, for use in the protection of phenols and carboxylic acids. It undergoes condensation reactions with aldehydes in the presence of SnCl2 or SmI3 to afford α,β-unsaturated ketones. It is also useful in the esterification of carboxylic acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2,4′-Dibromoacetophenone is used as a reagent for analysis of fatty acids by HPLC as 4-bromophenacyl esters, for use in the protection of phenols and carboxylic acids. It undergoes condensation reactions with aldehydes in the presence of SnCl2 or SmI3 to afford α,β-unsaturated ketones. It is also useful in the esterification of carboxylic acids.

Solubility
Soluble in dimethyl sulfoxide (5 mg/ml), methanol (20 mg/ml), toluene and ethanol. Insoluble in water.

Notes
Keep container tightly sealed. Store in refrigerated condition. Incompatible with bases and oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 99-73-0
Molecular Formula C8H6Br2O
Molecular Weight (g/mol) 277.943
MDL Number MFCD00000200
InChI Key FKJSFKCZZIXQIP-UHFFFAOYSA-N
Synonym 2,4'-dibromoacetophenone, 2-bromo-1-4-bromophenyl ethanone, 4-bromophenacyl bromide, p-bromophenacyl bromide, ethanone, 2-bromo-1-4-bromophenyl, 4'-bromophenacyl bromide, p-bromophenacyl-8, alpha,p-dibromoacetophenone, alpha,4-dibromoacetophenone, 4-bromo bromoacetyl benzene
PubChem CID 7454
IUPAC Name 2-bromo-1-(4-bromophenyl)ethanone
SMILES C1=CC(=CC=C1C(=O)CBr)Br

Specifications

Melting Point 108°C to 112°C
Odor Pungent
Quantity 25 g
UN Number UN3261
Beilstein 607604
Merck Index 14,1427
Solubility Information Soluble in dimethyl sulfoxide (5mg/ml),methanol (20mg/ml),toluene and ethanol. Insoluble in water.
Formula Weight 277.95
Percent Purity ≥98%
Chemical Name or Material 2,4'-Dibromoacetophenone
Hazard Category H314
Hazard Statement GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
Precautionary Statement P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
DOTInformation Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber 202-783-6
RTECSNumber AM6950000
TSCA Yes
Recommended Storage Keep cold

RUO – Research Use Only

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