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Sigma Aldrich 3-(4-FLUOROPHENYL)-5-METHYLISOXAZOL-4-OL

Catalog No. JRD03021G Shop All MilliporeSigma Sigma Organic Chemistry Products
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JRD03021G 25 mL
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

  • Ethyl phenylphosphinate is an organophosphorous compound. it undergoes regioselective markovnikov addition reaction with terminal alkynes in the presence of palladium-1,2-bis(diphenylphosphino)ethane complex (catalyst). ethyl phenylphosphinate is the photodecomposition product of inezin (s-benzyl o-ethyl phenylphosphonothiolate) on the ultraviolet irradiation. it can be prepared by the reaction of phosphinic acid with ethyl chloroformate in the presence of pyridine. its ethylation using ethyl trimethylsilyl phenylphosphonite or the corresponding trimethylstannyl ester has been described. its free-radical addition to ethylene has been reported to proceed with the retention of configuration.ethyl phenylphosphinate may be used in the preparation of the following diethyl imidazol-2-yl-(amino) methylphosphonates and phosphinates:
  • Imidazol-2-yl-methyl(n-butylamino)phosphonate diethyl ester
  • Imidazol-2-yl-methyl(n-benzylamino)phosphonate diethyl ester
  • Imidazol-2-yl-methyl(n-butylamino)phenylphosphinate ethyl ester
  • Imidazol-2-yl-methyl(n-benzylamino)phenylphosphinate ethyl ester

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