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4-(Dimethylamino)pyridine, 99%

Catalog No. AAA1301606
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Quantity:
5 g
25 g
100 g

CAS: 1122-58-3 | C7H10N2 | 122.171 g/mol

4-(Dimethylamino)pyridine is a useful nucleophilic catalyst for various reactions viz. esterifications with anhydrides, the Baylis-Hillman reaction, hydrosilylations, tritylation and Steglich rearrangement. It is also an effective catalyst for transesterification of beta-keto esters and silylation of alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-(Dimethylamino)pyridine is a useful nucleophilic catalyst for various reactions viz. esterifications with anhydrides, the Baylis-Hillman reaction, hydrosilylations, tritylation and Steglich rearrangement. It is also an effective catalyst for transesterification of beta-keto esters and silylation of alcohols.

Solubility
Soluble in methanol, benzene, ethyl acetate, chloroform, methylene chloride, acetone, and acetic acid. Slightly soluble in ether, diisopropyl ether, cyclohexane, hexane, and water.

Notes
Incompatible with strong oxidizing agents and strong acids.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 1122-58-3
Molecular Formula C7H10N2
Molecular Weight (g/mol) 122.171
MDL Number MFCD00006418
InChI Key VHYFNPMBLIVWCW-UHFFFAOYSA-N
Synonym 4-dimethylaminopyridine, dmap, 4-dimethylamino pyridine, 4-pyridinamine, n,n-dimethyl, n,n-dimethyl-4-pyridinamine, p-dimethylaminopyridine, pyridine, 4-dimethylamino, ccris 6176, dimethylpyridin-4-ylamine
PubChem CID 14284
IUPAC Name N,N-dimethylpyridin-4-amine
SMILES CN(C)C1=CC=NC=C1

Specifications

Melting Point 110°C to 113°C
Boiling Point 162°C (50 mmHg)
Flash Point 124°C (255°F)
Assay Percent Range 99%
Quantity 5 g
UN Number UN2928
Beilstein 110354
Solubility Information Soluble in methanol,benzene,ethyl acetate,chloroform,methylene chloride,acetone,and acetic acid. Slightly soluble in ether,diisopropyl ether,cyclohexane,hexane,and water.
Formula Weight 122.17
Percent Purity 99%
Chemical Name or Material 4-(Dimethylamino)pyridine
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Hazard Category H301+H331-H310-H315-H318-H370
Hazard Statement GHS H Statement
H301-H310-H314-H318
Toxic if swallowed.
Fatal in contact with skin.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Precautionary Statement P260-P262-P264b-P270-P271-P280-P301+P310-P302+P350-P304+P340-P305+P351+P338-P307+P311-P310-P311-P330-P332+P313-P361-P363-P501c
DOTInformation Hazard Class: 6.1; Packaging Group: II
EINECSNumber 214-353-5
RTECSNumber US9230000
TSCA Yes
Recommended Storage Ambient temperatures

RUO – Research Use Only

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