Alfa Aesar™ 4-(Methoxycarbonyl)benzeneboronic acid, 97%

Manufacturer: Alfa Aesar™ H2762703

Quantity 1g

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Catalog No. AAH2762703

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    Chemical Identifiers

    CAS 99768-12-4
    Molecular Formula C8H9BO4
    Formula Weight 179.97g/mol
    MDL Number MFCD01632203
    Synonym 4-(Methoxycarbonyl)phenylboronic acid; Methyl 4-boronobenzoate
    Chemical Name or Material 4-(Methoxycarbonyl)benzeneboronic acid

    Specifications

    Melting Point 220° to 225°C
    Quantity 1g
    CAS 99768-12-4
    Molecular Formula C8H9BO4
    Formula Weight 179.97g/mol
    MDL Number MFCD01632203
    Synonym 4-(Methoxycarbonyl)phenylboronic acid; Methyl 4-boronobenzoate
    Health Hazard 1 Warning
    Health Hazard 2 GHS H Statement
    H315-H319-H335
    Causes skin irritation.
    Causes serious eye irritation.
    May cause respiratory irritation.
    Health Hazard 3 GHS P Statement
    P261-P280-P305+P351+P338-P304+P340-P405-P501a
    Avoid breathing dust/fume/gas/mist/vapors/spray.
    Wear protective gloves/protective clothing/eye protection/face protection.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.
    Chemical Name or Material 4-(Methoxycarbonyl)benzeneboronic acid
    Assay 97%

    Description

    Applications
    It is a reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration and cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. It is employed as reagent in Reagent used in preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid, chromenones and their bradykinin B1 antagonistic activity, Pt nanoparticles on Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injection and salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

    Solubility
    Soluble in methanol.

    Notes
    Store in cool dry conditions. Incompatible with oxidizing agents. Ensure good ventilation.

    GHS H Statement
    H315-H319-H335
    Causes skin irritation.
    Causes serious eye irritation.
    May cause respiratory irritation.

    GHS P Statement
    P261-P280-P305+P351+P338-P304+P340-P405-P501a
    Avoid breathing dust/fume/gas/mist/vapors/spray.
    Wear protective gloves/protective clothing/eye protection/face protection.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
    IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
    Store locked up.
    Dispose of contents/container in accordance with local/regional/national/international regulations.

    Warning

    SDS & Safety Documents

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