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Description
- Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) is a sterically hindered, weakly -g-donating and strongly -accepting ligand. it can be prepared by the reaction of lithium salt of 1,1,1,3,3,3-hexafluoro-2-propoxide with pcl3. it reacts with nucleosides to form deoxyribonucleoside 3α-bis(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite units.tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) may be used in the following processes:
- Preparation of new phosphonylating and coupling agents for the synthesis of oligodeoxyribonucleotides
- Preparation of nucleoside h-phosphonate units
- Synthesis of tetrakis(1,1,1,3,3,3-hexafluoroisopropoxy)(phenylthio)phosphorane by reacting with 1,1,1,3,3,3-hexafluoroisopropyl benzenesulfenate
Specifications
Specifications
| CAS | 1144-74-7 |
| Melting Point | 136°C to 138°C (lit.) |
| Molecular Formula | C13H9NO3 |
| Linear Formula | O2NC6H4COC6H5 |
| MDL Number | MFCD00007354 |
| Quantity | 1 g |
| Molecular Weight (g/mol) | 227.22 |
| Percent Purity | 99% |
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