Allyltrimethylsilane, 98+%

Description

CAS: 762-72-1 | C6H14Si | 114.263 g/mol

Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.

Solubility
Miscible with organic solvents. Immiscible with water.

Notes
Store in cool place. Incompatible with strong oxidizing agents and acids.

Specifications

Chemical Identifiers

• CAS: 762-72-1
• Molecular Formula: C6H14Si
• Molecular Weight (g/mol): 114.263
• MDL Number: MFCD00008635
• InChI Key: HYWCXWRMUZYRPH-UHFFFAOYSA-N
• Synonym: allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane
• PubChem CID: 69808
• IUPAC Name: trimethyl(prop-2-enyl)silane
• SMILES: C[Si](C)(C)CC=C

• Boiling Point: 85°C to 86°C
• Quantity: 50 g
• UN Number: UN1993
• Beilstein: 906755
• Flash Point: −10°C (14°F)
• Solubility Information: Miscible with organic solvents. Immiscible with water.
• Formula Weight: 114.27
• Percent Purity: ≥98%
• Refractive Index: 1.408
• Density: 0.717
• Chemical Name or Material: Allyltrimethylsilane

Safety and Handling

Hazard Category	H225-H315-H319-H335
Hazard Statement	GHS H Statement H225-H315-H319-H335 Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
EINECSNumber	212-104-5
TSCA	Yes
Recommended Storage	Ambient temperatures

SDS

RUO – Research Use Only