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Sigma Aldrich Berkessel-Katsuki Epoxidation Catalyst

Catalog No. 900768100MG Shop All MilliporeSigma Sigma Organic Chemistry Products
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90-076-8100MG 1 mg
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Developed by Albrecht Berkessel's lab, this is the first catalyst that allows catalytic enantioselective epoxidation of non-conjugated terminal double bonds with hydrogen peroxide as the oxidant. Eradicating multiple steps and kinetic resolution, this pre-formed chiral ligand-Ti2O2 catalyst complex provides a one-step route to enantiopure epoxides that are important intermediates for synthesis of bioactive compounds. Catalyst is recyclable under some conditions. For best results, pentafluorobenzoic acid P5360 or tetra-n-butylammonium hydrogensulfate 155837 is recommended as a co-catalyst.Titanium cis-1,2-Diaminocyclohexane Salalen Catalysts of Outstanding Activity and Enantioselectivity for the Asymmetric Epoxidation of Nonconjugated Terminal Olefins with Hydrogen Peroxide

Specifications

CAS 1394957-71-1
Molecular Formula C13H18N5O13P3 -+ xNa+
Linear Formula C13H18N5O13P3 -+ xNa+
Quantity 1 mg
Synonym (N6pATP) sodium salt; N6-Propargyl-adenosine-5'-triphosphate sodium salt
Molecular Weight (g/mol) 545.23 (free acid basis) g/mol
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