Bis(1,5-cyclooctadiene)nickel(0), 96%

Description

CAS: 1295-35-8 | C16H24Ni | 275.06 g/mol

Catalyst for isomerization and hydrosilyltion of unsaturated compounds. Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. It is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Catalyst for isomerization and hydrosilyltion of unsaturated compounds
• Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, butadiene

Specifications

Chemical Identifiers

• CAS: 1295-35-8
• Molecular Formula: C16H24Ni
• Molecular Weight (g/mol): 275.06
• MDL Number: MFCD00058902
• InChI Key: JRTIUDXYIUKIIE-KZUMESAESA-N
• Synonym: bis 1,5-cyclooctadiene nickel 0, bis 1,5-cyclooctadiene nickel, ni cod 2, ccris 5973, bis cyclooctadiene nickel 0, nickel, bis 1,5-cyclooctadiene, bis cyclooctadiene nickel, 1z,5z-cycloocta-1,5-diene; nickel, nickel biscod, pubchem16018
• PubChem CID: 6433264
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;nickel
• SMILES: [Ni].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

• Melting Point: 60°C (decomposition)
• Color: Yellow
• Odor: Odorless
• Quantity: 2 g
• UN Number: UN1325
• Sensitivity: Air and light sensitive
• Solubility Information: Soluble in benzene,toluene,terahydrofuran,ether,dimethyl formamide,hexamethylphosphoramide,N-methylpyrrolidinone. Insoluble in water.
• Formula Weight: 275.06
• Percent Purity: 96%
• Physical Form: Powder
• Chemical Name or Material: Bis (1,5-cyclooctadiene)nickel (0)

Safety and Handling

Hazard Category	H228-H317-H350
Hazard Statement	GHS H Statement H228-H350-H317 Flammable solid. May cause cancer. May cause an allergic skin reaction.
Precautionary Statement	P201-P202-P210-P240-P241-P261-P270-P272-P280-P302+P352-P308+P313-P333+P313-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 4.1; Packing Group: II; Proper Shipping Name: FLAMMABLE SOLIDS, ORGANIC, N.O.S.
EINECSNumber	215-072-0
RTECSNumber	QR6135000
TSCA	No
storageNote1	Packaged under argon
Recommended Storage	Ambient temperatures; Store under Nitrogen

SDS

RUO – Research Use Only