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Sigma Aldrich Borane Dimethyl Sulfide Complex

Catalog No. 179825100ML Shop All MilliporeSigma Sigma Organic Chemistry Products
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17-982-5100ML 100 mL
50-308-1437 25 mL
17-982-525ML 4 x 25 mL
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MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Borane dimethyl sulfide complex (BMS) is a commonly used reagent and a mediator for hydroboration reaction for the preparation of organoborane compounds, which are utilized as key intermediates in organic synthesis. BMS is also employed as a reducing agent for the reduction of various functional groups such as aldehydes, ketones, epoxides, esters, and carboxylic acids to corresponding alcohols.Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent: For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate. For the conversion of ozonides to alcohols. In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand. For the hydroboration reduction and other applications. With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.10.0-10.2 M as BH3. May contain excess methyl sulfide.Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Specifications

CAS 13292-87-0
Density 0.801 g/mL at 25°C
Molecular Formula C2H9BS
Linear Formula (CH3)2S -+ BH3
MDL Number MFCD00013189
Quantity 100 mL
Synonym (Dimethyl sulfide)trihydroboron; BMS; Borane-dimethyl sulfide
Molecular Weight (g/mol) 75.97 g/mol
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