Sigma Aldrich Borane Dimethyl Sulfide Complex

Catalog No.	Quantity
50-308-1437	25 mL
17-982-5100ML	100 mL
17-982-525ML	4 x 25 mL
17-982-5800ML	800 mL

Catalog No. 50-308-1437

Supplier: Sigma Aldrich 17982525ML

Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Borane dimethyl sulfide complex (BMS) is a commonly used reagent and a mediator for hydroboration reaction for the preparation of organoborane compounds, which are utilized as key intermediates in organic synthesis. BMS is also employed as a reducing agent for the reduction of various functional groups such as aldehydes, ketones, epoxides, esters, and carboxylic acids to corresponding alcohols.Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent: For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate. For the conversion of ozonides to alcohols. In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand. For the hydroboration reduction and other applications. With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.10.0-10.2 M as BH3. May contain excess methyl sulfide.Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Specifications

• CAS: 13292-87-0
• Density: 0.801 g/mL at 25°C
• Molecular Formula: C2H9BS
• Linear Formula: (CH3)2S -+ BH3
• Quantity: 25 mL
• MDL Number: MFCD00013189
• Synonym: (Dimethyl sulfide)trihydroboron; BMS; Borane-dimethyl sulfide
• Molecular Weight (g/mol): 75.97 g/mol