Borane-dimethyl sulfide complex, 2M in toluene, packaged under Argon in resealable ChemSeal™ bottles

Description

CAS: 13292-87-0 | C2H9BS | 75.96 g/mol

Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Packaged under Argon

Specifications

Chemical Identifiers

• CAS: 13292-87-0
• Molecular Formula: C2H9BS
• Molecular Weight (g/mol): 75.96
• MDL Number: MFCD00013189
• InChI Key: RMHDLBZYPISZOI-UHFFFAOYSA-N
• Synonym: dimethyl sulfide borane, borane-methyl sulfide complex, borane dimethyl sulfide complex, borane-dimethyl sulfide, dimethyl sulfideborane, dimethyl sulfide trihydroboron, borane-dimethyl sulfide complex, borane methylsulfide, borane dimethylsulfide, borane dms
• PubChem CID: 9833925
• IUPAC Name: boron;methylsulfanylmethane
• SMILES: B.CSC

• Color: Colorless
• Density: 0.856 g/mL
• Flash Point: 7°C (45°F)
• Packaging: ChemSeal™ bottles
• Linear Formula: (CH₃)₂S·BH₃
• Quantity: 100 mL
• UN Number: UN3399
• Beilstein: 3663489
• Sensitivity: Air and moisture sensitive
• Solubility Information: It reacts with water. Miscible with diethyl ether,methylene chloride,hexane,heptane,petroleum ether,tetrahydrofuran,diglyme,benzene,toluene and xylene.
• Formula Weight: 75.97
• Concentration or Composition (by Analyte or Components): 2M in toluene
• Physical Form: Liquid
• Chemical Name or Material: Borane-dimethyl sulfide complex

Safety and Handling

Hazard Category	H225-H260-H302-H304-H315-H318-H335-H336-H361d-H373
Hazard Statement	GHS H Statement H225-H260-H300-H304-H361-H373-H314-H336 Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. Fatal if swallowed. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. May cause drowsiness or dizziness.
Precautionary Statement	P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P331-P332+P313-P335
DOTInformation	Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA	Yes
storageNote1	Packaged under Argon
Recommended Storage	Ambient temperatures; Store under Argon

SDS

RUO – Research Use Only