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  6. Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%

Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%

Catalog No. AA1274901
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Catalog No. AA1274901 Supplier Thermo Scientific Chemicals Supplier No. 01274901
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Description

CAS: 12112-67-3 | C16H24Cl2Ir2 | 671.70 g/mol

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 12112-67-3
Molecular Formula C16H24Cl2Ir2
Molecular Weight (g/mol) 671.70
MDL Number MFCD00012414
InChI Key ZFOUDQNHNLDNLD-MIXQCLKLSA-L
Synonym chloro 1,5-cyclooctadiene iridium i dimer, bis 1,5-cyclooctadiene diiridium i dichloride, 1z,5z-cycloocta-1,5-diene; iridium; dichloride, iridium, di-.mu.-chlorobis 1,2,5,6-.eta.-1,5-cyclooctadiene di, ir2cl2 cod 2, chloro-1,5-cyclooctadiene iridium i dimer, 1z,5z-cycloocta-1,5-diene; iridium 1+
PubChem CID 6436381
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride
SMILES [Cl-].[Cl-].[Ir+].[Ir+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

Specifications

Melting Point 190°C (decomposition)
Color White
Odor Odorless
Quantity 0.25 g
Solubility Information Soluble in chloroform and toluene. Slightly soluble in acetone and alcohol. Insoluble in water.
Formula Weight 671.71
Physical Form Crystalline Powder
Chemical Name or Material Chloro(1, 5-cyclooctadiene)iridium(I) dimer

Safety and Handling

Hazard Category H315-H319-H335
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
EINECSNumber 235-170-7
TSCA No
Recommended Storage Ambient temperatures
SDS

RUO – Research Use Only

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