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Sigma Aldrich Chlorodicyclohexylphosphine

Catalog No. 4814085G Shop All MilliporeSigma Sigma Organic Chemistry Products
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of: 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis-Arbuzov type rearrangements.1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.

Specifications

CAS 16523-54-9
Density 1.054 g/mL at 25°C
Boiling Point 165°C (12 mmHg, lit.)
Molecular Formula C12H22ClP
Refractive Index n20/D 1.533
Linear Formula (C6H11)2PCl
MDL Number MFCD00014294
Quantity 5 g
Synonym Dicyclohexylchlorophosphine; Dicyclohexylphosphine chloride; Dicyclohexylphosphinous chloride
Molecular Weight (g/mol) 232.73 g/mol
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