(Chloromethyl)cyclopropane, 97%

Description

CAS: 5911-08-0 | C4H7Cl | 90.55 g/mol

(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.

Solubility
Not miscible in water.

Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents, bases and heat.

Specifications

Chemical Identifiers

• CAS: 5911-08-0
• Molecular Formula: C4H7Cl
• Molecular Weight (g/mol): 90.55
• MDL Number: MFCD00001307
• InChI Key: ZVTQWXCKQTUVPY-UHFFFAOYSA-N
• Synonym: chloromethyl cyclopropane, cylopropylmethyl chloride, cyclopropylmethyl chloride, cyclopropane, chloromethyl, chloromethyl-cyclopropane, j7okqcc0kw, unii-j7okqcc0kw, cylopropylmethylchloride, chlorocyclopropylmethane, cyclopropylchloromethane
• PubChem CID: 80013
• SMILES: ClCC1CC1

• Melting Point: -91°C
• Density: 0.98
• Boiling Point: 87°C to 89°C
• Flash Point: −1°C (30°F)
• Odor: Recognizable
• Refractive Index: 1.436
• Quantity: 5 g
• UN Number: UN1993
• Beilstein: 635697
• Solubility Information: Not miscible in water.
• IUPAC Name: chloromethylcyclopropane
• Formula Weight: 90.55
• Percent Purity: 97%
• Chemical Name or Material: (Chloromethyl)cyclopropane

Safety and Handling

Hazard Category	H225-H302
Hazard Statement	GHS H Statement H225-H302-H315-H319-H335 Highly flammable liquid and vapor. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P210-P233-P240-P241-P242-P243-P264b-P270-P280-P301+P312-P303+P361+P353-P330-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
EINECSNumber	227-632-1
TSCA	No
Recommended Storage	Keep cold

SDS

RUO – Research Use Only