Dibenzyl carbonate, 98%

Description

CAS: 3459-92-5 | C15H14O3 | 242.27 g/mol

Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.

Solubility
Sparingly Soluble (0.099 g/L) (25°C).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heat.

Specifications

Chemical Identifiers

• CAS: 3459-92-5
• Molecular Formula: C15H14O3
• Molecular Weight (g/mol): 242.27
• MDL Number: MFCD00014436
• InChI Key: PIZLBWGMERQCOC-UHFFFAOYSA-N
• Synonym: carbonic acid, bis phenylmethyl ester, benzyl carbonate, carbonic acid, dibenzyl ester, dibenzylcarbonate, carbonic acid dibenzyl ester, phenylmethyl phenylmethoxy formate, dibenzyl carbonate, acmc-209i8r, carbonic acid,bis phenylmethyl ester
• PubChem CID: 77002
• IUPAC Name: dibenzyl carbonate
• SMILES: O=C(OCC1=CC=CC=C1)OCC1=CC=CC=C1

• Melting Point: 27°C to 30°C
• Boiling Point: 150°C to 155°C (0.8 mmHg)
• Flash Point: >110°C (230°F)
• Refractive Index: 1.5485
• Quantity: 10 g
• Beilstein: 1882864
• Sensitivity: Air sensitive
• Solubility Information: Sparingly Soluble (0.099g/L) (25°C).
• Formula Weight: 242.27
• Percent Purity: 98%
• Chemical Name or Material: Dibenzyl carbonate

Safety and Handling

Hazard Category	H302+H312
Precautionary Statement	P264b-P270-P280-P301+P312-P302+P352-P312-P330-P363-P501c
EINECSNumber	222-401-1
TSCA	Yes
Recommended Storage	Keep cold; Store under Argon

SDS

RUO – Research Use Only