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Sigma Aldrich Dihydrophenazine Pc(Tm) B0301

Catalog No. 901112100MG Shop All MilliporeSigma Sigma Organic Chemistry Products
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Catalog No. Quantity
90-111-2100MG 10 mg
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Catalog No. 90-111-2100MG

Supplier: Sigma Aldrich 901112100MG

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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

This dihydrophenazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst 901111) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with the Miyake Research Group.Strongly Reducing Visible Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious MetalsOrganocatalyzed Atom Transfer Radical Polymerization Driven by Visible LightOrganocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox CatalystsIntramolecular Charge Transfer and Ion Pairing in N, N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical PolymerizationPhenox O-PC is a trademark of New Iridiu mLLC

Specifications

CAS 1594113-05-9
Molecular Formula C16H28N4O4S -+ C2HF3O2
Linear Formula C16H28N4O4S -+ C2HF3O2
Quantity 10 mg
Synonym (R)-2-Ammonio-6-(5-((3aR,4R,6aS)-2-oxohexahydro-1H-thieno[3,4-d]imidazol-4-yl)pentanamido)hexanoate 2,2,2-trifluoroacetate; BDL TFA salt
Molecular Weight (g/mol) 486.51 g/mol
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