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Sigma Aldrich (Dimethylphenylsilyl)Boronic Acid Pinacol Ester

Catalog No. 6834345G Shop All MilliporeSigma Sigma Organic Chemistry Products
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68-343-45G 100 mg
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MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

(Dimethylphenylsilyl)boronic acid pinacol ester (Suginome'sas reagent) can be used as a reagent: For the selective addition of dimethylphenylsilanyl group to cyclic and acyclic unsaturated ketones, esters, acrylonitriles using a copper catalyst. In the synthesis of (Z)-4-boryl-1-silyl-2-alkene derivatives by stereoselective addition of silicon-boron bond to acyclic 1,3-dienes in presence of Ni catalyst. In the preparation of silyl-substituted butenoate and +a-silyl-substituted acrylate derivatives from allenes and propiolate derivatives via hydrosilylation reactions using a copper catalyst. In the palladium-catalyzed asymmetric silaboration of allenes and alkanes to offered corresponding +a-borylallylsilanes and 2-boryl-1-silylalkanes respectively.

Specifications

CAS 1107608-80-9
Melting Point 100°C to 105°C
Molecular Formula C18H28N2P2
Linear Formula C18H28N2P2
Refractive Index n20/D 1.4946
MDL Number MFCD10567042
Quantity 100 mg
Synonym 2-(Dimethylphenylsilyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; B-(dimethylphenylsilyl)pinacolborane
Molecular Weight (g/mol) 334.38 g/mol
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