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Sigma Aldrich Endo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine

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79-843-6100MG 100 mg
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

The bicyclic, chiral phosphine was developed by the Kwon Research Group. Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-PyrrolinesTechnology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from HydroxyprolineAldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations

Specifications

CAS 62327-21-3
Density 1.131 g/mL at 20°C
Boiling Point 86°C to 87°C (0.02 mmHg, lit.)
Molecular Formula C8H17O5P
Linear Formula (CH3O)2P(O)CH2COOC(CH3)3
Quantity 100 mg
MDL Number MFCD00042939
Molecular Weight (g/mol) 224.19 g/mol
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