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Sigma Aldrich Ethyl 4,4,4-trifluoroacetoacetate

Catalog No. E50205100G Shop All MilliporeSigma Sigma Organic Chemistry Products
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E50205100G 100 g
E5020525G 25 g
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Description

MilliporeSigma Sigma Organics products encompass a wide range of quality reagents, solvents, catalysts, and building blocks for organic synthesis. From benchtop discovery to process development and scale-up, Sigma Organics solutions are built to meet the needs of synthetic chemists.

  • Ethyl 4,4,4-trifluoroacetoacetate (etfaa) is a general reagent to synthesize enantiopure trifluoromethyl-functionalized products. applications include:
  • Synthesis of (s)- and (r)-α-trifluoromethyl-aspartic acid and α- trifluoromethyl-serine from chiral cf3-oxazolidines, which is derived from etfaa
  • Enantiopure synthesis of trifluoromethyl-α-amino acid derivatives
  • Synthesis of (2r)-2-trifluoromethyl-2-carboxyazetidine, (r)- and (s)-trifluoromethylhomoserines from oxazolidine intermediate obtained by condensing (r)-phenylglycinol with etfaa

Specifications

CAS 372-31-6
Density 1.259 g/mL (at 25°C (literature))
Boiling Point 129°C to 130°C (lit.)
Molecular Formula C6H7F3O3
Refractive Index n20/D 1.375 (literature)
Linear Formula CF3COCH2CO2C2H5
MDL Number MFCD00000424
Quantity 100 g
Synonym ETFAA; Ethyl 3-oxo-4,4,4-trifluorobutyrate
Molecular Weight (g/mol) 184.11
Percent Purity 99%
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