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Sigma Aldrich Ethyl 5-methyl-4-oxo-3,4-dihydrothieno[2,3-d]pyrimidine-6-carboxylate
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Description
- Formaldehyde diethyl acetal (fdea, diethoxymethane, dem) is a diethyl acetal
- It has been synthesized from ethanol and aqueous formaldehyde
- It is a low boiling solvent useful for sodium hydride reactions, organolithium chemistry, copper-catalyzed conjugate additions and phase-transfer reactions
- It is a potential alternate for tetrahydrofuran, dichloromethane, glyme and methylal
- Dem is an ethoxymethylating agent, a formaldehyde equivalent and a carbonylation substrate
- Its condensation with 2-propylresorcinol to form resorcin[n]arenes (n=4-7) has been investigated
- The IR and raman spectra and conformations of dem have been studied
- NMR spectroscopy has been used to study the aggregation behavior of organolithium compounds in diethoxymethane
- Unimolecular metastable decomposition of dem upon electron impact has been studied
- Solubility of non-polar gases in dem has been evaluated.formaldehyde diethyl acetal may be used as a solvent in the esterification of carboxylic acids and in the o-alkylation of a variety of phenols
Specifications
Specifications
| CAS | 17417-67-3 |
| Molecular Formula | C10H10N2O3S |
| Linear Formula | C10H10N2O3S |
| MDL Number | MFCD00168240 |
| Quantity | 500 mL |
| Molecular Weight (g/mol) | 238.26 |
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