Ethyltriphenylphosphonium bromide, 98+%

Description

CAS: 1530-32-1 | C20H20BrP | 371.26 g/mol

Ethyltriphenylphosphonium bromide acts as a reactant in the synthesis of D-amino acids from L-cysteine-derived thiazolidines, Leiodolide A through aldol reactions and Horner-Wadsworth-Emmons olefination. It is also used in the preparation of cycloalkanoindolines through diastereoselective intramolecular inimo-ene reactions. Further, it is used as a reagent in solid-state metathesis polycondensation to prepare alkyl-dipropenylthiophene monomers and Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ethyltriphenylphosphonium bromide acts as a reactant in the synthesis of D-amino acids from L-cysteine-derived thiazolidines, Leiodolide A through aldol reactions and Horner-Wadsworth-Emmons olefination. It is also used in the preparation of cycloalkanoindolines through diastereoselective intramolecular inimo-ene reactions. Further, it is used as a reagent in solid-state metathesis polycondensation to prepare alkyl-dipropenylthiophene monomers and Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization reactions.

Solubility
Soluble in methanol. Slightly soluble in water, acetone and isopropanol.

Notes
Hygroscopic. Incompatible with oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 1530-32-1
• Molecular Formula: C20H20BrP
• Molecular Weight (g/mol): 371.26
• MDL Number: MFCD00011838
• InChI Key: JHYNXXDQQHTCHJ-UHFFFAOYSA-M
• Synonym: ethyltriphenylphosphonium bromide, ethyl triphenyl phosphonium bromide, triphenylethylphosphonium bromide, phosphonium, ethyltriphenyl-, bromide, ethyltriphenylphosphanium bromide, ethyl triphenylphosphonium bromide, unii-r85v84ul5v, ethyltriphenylphosphoniumbromide, guaifenesin powder, pubchem18705
• PubChem CID: 73727
• SMILES: [Br-].CC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

• Melting Point: 206°C to 210°C
• Flash Point: >200°C (392°F)
• Odor: Odorless
• Linear Formula: CH₃CH₂P(C₆H₅)₃Br
• Quantity: 500 g
• UN Number: UN3077
• Beilstein: 3599630
• Sensitivity: Hygroscopic
• Solubility Information: Soluble in methanol. Slightly soluble in water,acetone and isopropanol.
• IUPAC Name: ethyl(triphenyl)phosphanium;bromide
• Formula Weight: 371.26
• Percent Purity: ≥98%
• Chemical Name or Material: Ethyltriphenylphosphonium bromide

Safety and Handling

Hazard Category	H301-H319-H500
Hazard Statement	GHS H Statement H302-H312-H315-H319-H335 Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P264b-P270-P280i-P301+P310-P305+P351+P338-P330-P501c
DOTInformation	Hazard Class: 6.1; Packaging Group: III
EINECSNumber	216-223-3
TSCA	Yes
Recommended Storage	Ambient temperatures; Store under Nitrogen

SDS

RUO – Research Use Only